The change in Gibbs free energy is also related to change in entropy for the universe: ΔG = -TΔSuniv (again through some algebra). Using the above equations and some algebra we can construct the formula: ΔG = ΔH – TΔSsyt, where ΔG is the change in free energy for the system. ![]() The opposite effect happens for an endothermic reaction.Īnd then finally probably the most useful formula is Gibbs free energy which measures how spontaneous a reaction is. So if a reaction is exothermic, a negative change in enthalpy, heat is given off by the reaction and is dispersed into the surroundings causing an increase in the surrounding’s entropy. It’s important to note the negative sign in the equation which means that the change in enthalpy for the system creates an opposite signed entropy change in the surroundings. And it only works at specific temperatures (different values of T cause different changes in entropy) since entropy is temperature dependent. This equation only works at constant pressure since enthalpy equals heat only at constant pressure. Since a change in entropy (and enthalpy) for a system creates an accompanying change in entropy for the surroundings we can use the formula: ΔSsur = -ΔHsyt/T, where ΔHsyt is the change in enthalpy for the system, and T is temperature in kelvins. The change in enthalpy for a reaction we can determine experimentally using calorimetry. But we can relate the change in the surrounding’s entropy to another thermodynamic quantity we know well, the enthalpy change of the system. Measuring the change in entropy for a system is relatively easy, but measuring the change in entropy for the surroundings is less easy to do directly. Using this formula we can judge if a reaction is spontaneous or not based on whether its change in entropy, and the surrounding accompanying change in entropy, facilitates a positive or negative change in entropy for the universe (following the second law). Together we get a formula for the overall change of entropy based on the system and surroundings: ΔSuniv = ΔSsyt + ΔSsur, where ΔSsyt is the change in the entropy of the system and ΔSsur is the change in the entropy of the surroundings. ![]() And the entropy of the surroundings (everything but the system itself) also being influenced by the entropy of the system. ![]() So we can imagine a reaction as a system whose entropy we care about. Usually when we do chemistry though we’re concerned not so much directly with the entropy of the universe, but rather the entropy change which accompanies a chemical reaction. This is why gas particles spread out in a container instead of concentrate themselves into a small area. The law and the formula essentially state that the universe naturally prefers greater levels of entropy and allows any process which causes a positive increase, but prohibits any process which causes a negative increase. A spontaneous process is one which happens naturally without the need of outside energy or work to help it along. So W is measuring how many energetically equivalent microstates a system can organize its energy into to get the same macrostate (or the system as we can observe it on a human scale).Īnother formula uses the second law of thermodynamics: ΔSuniv > 0, which put into words states that any spontaneous process increases the entropy of the universe (creates a positive change). A microstate is a particular way to order energy. Boltzmann’s formula uses a more mathematical approach to entropy by using W. The unit for entropy is the same as Boltzmann’s constant which means that entropy can also be understood as how many energy can be dispersed at a certain temperature since entropy is temperature dependent. One equation is Boltzmann’s equation: S = k*ln(W), where S is entropy (the usual variable for entropy), k is Boltzmann’s constant which is equal to the gas constant divided by Avogadro’s number which is approximately equal to 1.38 x 10^(-23) J/K, and W is the number of microstates which is a unitless quantity. There are several because entropy can be explained and used in a variety of ways. Since entropy is primarily dealing with energy, it’s intrinsically a thermodynamic property (there isn’t a non-thermodynamic entropy).Īs far as a formula for entropy, well there isn’t just one. First it’s helpful to properly define entropy, which is a measurement of how dispersed matter and energy are in a certain region at a particular temperature.
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This systematic approach and the iceberg worksheet can dramatically enhance emotional intelligence and communication skills, helping students identify and express their vulnerable feelings in healthier ways.
![]() Applications of Female Voice Changer Apps.This article will introduce you to various applications of male-to-female voice changers and provide a list of the top seven voice changers of 2024, which includes popular options such as Murf, Audacity, and Voicemod. For example, comedians or performers may use a female voice changer as part of their act to add humor or pizzazz to their performance. There are various professional use cases for an Online voice changer, including voiceover work, the call center industry, and the entertainment industry. With a female voice changer app, users can alter the voiceover or their own voice to create a range of female voice types, such as a young girl, a mature woman, or a female cartoon character, and record videos as well. It's typically used in voice recording and live voice communication applications such as voice chat, video conferencing, and online gaming. This is where a female voice changer powered by cutting-edge artificial intelligence technology comes into the picture.Ī female voice changer app is a software tool that uses voice filters and allows you to modify your voice to sound like a woman or a girl. Moreover, there are also applications and software such as this list of voice changers for Mac which will help cover up the caller's real identity by creating a completely different voice or through sound effects.Today, a lot of people want to experiment and transform their voices into totally new characters or switch genders, like with an interesting female voice. One of the tricks to achieve a successful prank call is to change your voice during the call through the use of any of these male to female voice changers. Even famous personalities are doing prank calls and the videos of actual pranking are being released. It somehow became a form of entertainment and is even being done live or on air. In fact, practical jokes through telephones or prank calls are very popular worldwide nowadays. ![]() Even though the identity of that first recorded prank caller has been lost to history, that person has started a trend that probably will never die. ![]() By the early 1900s, pranksters were using slips to deceive people into becoming prank callers themselves. Apparently, the prankster keeps demanding over the phone for the undertakers to bring stuff for individuals alleged to be dead. The printed article was about a practical joke being played on the undertakers or morticians at Providence, R.I. He claims that he traced it from a newspaper printed way back February 2, 1884, "The Electrical World". After all, somehow, you can still place yourself in a situation that keeps your real identity, at least for a little while.ĭid you know that the first recorded prank phone call was from 1884? This is according to Paul Collins also known as "The Literary Detective". So, if you want to have some fun due to the fact that your voice is too distinct to recognize or for whatever reason, we can help you, In this list, we have some of the best apps to change your voice during calls. These free voice changer apps can turn your simple conversations into a funny laugh fest. Imagine turning your voice from male to female during calls. Even for online gaming or even making simple prank calls, one can find the best voice changer app for calls. This doesn't strictly go for live phone calls. A lot of these voice changer apps for live phone calls even have various sound effects and voice features available to add some more fun. What has become of people's privacy? Can we still be able to make phone calls to our loved ones without being identified and vice versa? Well, for people who wants to keep even a little bit of their identities for themselves, you can actually find ways on how to change your voice when calling someone. In the age of connectivity and information, everything seems to be accessible in matter of a few clicks and some typing. Social media has also made it easier to reveal our identities to the whole online world. With all the available resources to track someone online, it is almost impossible to go incognito for an extended period of time. Nowadays, there seems to be no hiding from the world. Raistlin brought the words to a spell to mind - one he had memorized centuries ago - and took out a pinch of bat guano. You can read the entire book when Dragons of Fate becomes available on Aug. Our excerpt picks up from an early meeting between Raistlin and Magius. ![]() It provides us, as readers making this journey with them, an opportunity to look inside of Sturm and inside of Raistlin in ways that we haven’t ever been able to before.” grapple with the reality that is, rather than his expectations. “Raistlin has always been so analytical and so distant anyway,” Hickman continued, “ trying to remove himself and observe everything from the outside, that I think we see the same viewpoint in him as he’s trying to grapple with these differences. He’s not the kind of guy who’s going to want to sit down with you and bare his soul. “Even though they’re confronting this real dissonance within them as they’re viewing their heroes, Sturm is reacting to it as Sturm would. “Sturm is still Sturm, and Raistlin is still Raistlin,” Hickman said. Hickman said the he and Weis have tried to remain faithful to their original characters, even when placing them within this new and unusual timeline. And now that they’ve met them, they have to deal with this.” “Raistlin and Sturm in particular have to struggle with this,” Weis said, “because Huma has always been Sturm’s hero and Magius Raistlin’s. And I think that, for us, having an opportunity to view Huma, to view Magius as people, as flawed individuals, and to get past the marble statues with them has been part of the journey of the book itself.” “We have a tendency to carve them in marble and make them perfect icons in our mind. “I think we all have a vision of our heroes,” Hickman said. Suddenly, the adventuring party finds themselves in the company of Magius and Huma Dragonbane, two legendary figures from Krynn’s past. Unfortunately, those actions pull her and members of the iconic Dragonlance Companions physically back in time. In Dragons of Deceit, Destina uses powerful magic to travel back in time with the hope of saving her kingdom in the land of Solamnia. Margaret and I to have a tendency to do very shattering second books, and this one feels like it follows that tradition.” It’s an explosive book with explosive events, and I’m very excited for people to take this part of the journey with us. ![]() “It’s not the tame second act by any stretch of the imagination. “The second book is explosive,” Hickman told Polygon in a recent interview. At the same time, it literally turns back the clock on the world of Krynn, placing fan-favorite characters Raistlin Majere and Sturm Brightblade once again at the center of the action. Dragons of Fate, the sequel to 2022’s Dragons of Deceit and the second novel in the Dragonlance Destinies series, continues the story of main character Destina Rosethorn. Authors Margaret Weis and Tracy Hickman, co-authors of the Dragonlance Dungeons & Dragons novels, are back with a powerful new book - and an exclusive excerpt for Polygon readers. ![]() Convert different types of files from iTunes, Apple Music, etc.ĭownloading files in various types of MPEG format.įree Trial Light- USD 9.99/month Basic- USD 14.99/month Unlimited- USD 25.99/month.Download channels and playlists in bulk without speed loss.Over 1000 devices and formats are supported.Utilizes built-in GPU and CPU to ensure faster conversions.Choose the one you want to convert the YouTube video or playlist into, and begin the processing quickly. In addition, it supports different types of output formats for the videos. With HitPaw, it is simple to download YouTube MPEG files after adding the preferred file type into the converter. Press the Settings button to make output configurations, rename the file, and choose a saving destination. ![]() Step5After completing all edits, click on the Export button at the top of the screen. Step4Click on the editing icons like Chroma Key, Keyframing, Splitting, Speed Revamp, Motion Tracking, etc., for custom changes. Step3Drag the videos you added for editing to the editor timeline at the lower end of the screen. Step2Press New Project > Click to insert the media file. Step1Launch the software on Mac or Windows device. 4K output quality for videos is not available for free.Some codecs are not supported in specific systems.Standard and advancing video editing features are available, like cropping, rotating, etc.Supports a wide range of video input and output formats.Supports different video codecs like MPEG4, and AV1.Works with ready-made settings for Huawaii, Android, Google, Sony, etc.The whole process took us a few taps to complete. You have to install the software, add the file through the device library, URL, or drag it to the editor, and choose the necessary customizations to convert. It works with different types of devices, browsers, and file formats. ![]() Freemake Video Downloaderįreemake Video Downloader is a suitable software to convert YouTube to MPEG4 format and download it. Now, onto a detailed explanation of each type of YouTube to MPEG4 converter software. MP4, MKV, MOV, MPEG-1, MPEG-2, AVI, TS, 3GP, GIF, WEBM, M2TS, MP3, WMV, etc. Quarterly- USD 29.99 Annual- USD 39.99 Perpetual- USD 55.99 One software to convert different file formats, DVD burn, screen recording, etc. MP4, MKV, MOV, MPEG-2, AVI, TS, 3GP, GIF, WEBM, MP3, WMV, F4V, etc.īuy the software for Windows and download converted file types after previewing the output video. Trial Monthly- USD 19.95 Annual- USD 39.95 Lifetime- USD 79.95 MP4, MKV, MOV, MPEG-2, AVI, TS, 3GP, GIF, WEBM, MP3, WMV, F4V, MPGĭownload videos from social media platforms like YouTube and convert them to MPEG format directly. MP4, MPEG-4, AVI, MP3, FLV, WMV, MKV, Apple, PSP, Android, etc.Ĭomprehensive video editing software with advanced features and convert files to the preferred format.įree Trial Monthly- USD 19.99 Annual- USD 49.99 Perpetual- USD 79.99 Easy to use software to encode and convert multiple media files into different codec-based types. ![]() Windstorm damage in Europe was shown not to increase after correcting for exposure increase 10 with attribution being complicated by contrasting trends in hazard 11 and very high uncertainty on vulnerability functions 12. Estimates on the value of assets in a given location (exposure) and flood vulnerability functions, which indicate the share of assets that are lost at a given intensity of flood, vary drastically between countries 6, 7, 8, 9. 5 has shown that flood protection was the biggest source of uncertainty in coastal flood risk assessments in test sites in the Iberian Peninsula. For example, flood risk in the Rhine basin was found to be least sensitive to change in atmospheric forcing, but more to changes in reservoir capacity, dike height, land use, asset value or private precautionary measures 4. Case studies have indicated strong influence of additional drivers especially for floods, where the uncertainty of the present risk is already high. However, less quantification is available for systems with strong non-climatic drivers of change 3. There is growing research that quantifies the effects of the changing climate on the world’s natural, managed and human systems 1, 2. Global mean temperature has surpassed 1 ☌ warming compared to pre-industrial times. This allows the separation of the effects of climate change from the effects of exposure change. Raster datasets generated by the model enable reconstructing exposure within the footprint of any extreme event both at the time of occurrence and anytime between 18. It consists of algorithms to reallocate baseline (2011) land use and population for any given year based on a large collection of historical subnational- and national-level statistics, and then disaggregate data on production and tangible assets by economic sector into a high-resolution grid. The HANZE v2.0 (Historical Analysis of Natural HaZards in Europe) dataset presented in this study quantifies the evolution of key socioeconomic drivers in Europe since 1870, namely land use, population, economic activity and assets. However, the effects of climate change are obscured in the observed impact data series due to the rapid evolution of the social and economic circumstances in which the events occurred. Understanding the influence of climate change on past extreme weather impacts is a vital research task. ![]() She is not native to Hallownest, originating from 'lands serene', a location from which she also brought Delicate Flowers. At the worst, you’ll have lost 20 seconds of your time, which honestly could have gone to worse things than sitting down and looking at your surroundings. Located in the Resting Grounds where she is known as the 'Grey Mourner', Zemer is the only remaining Great Knight besides Ogrim.Sheo refers to her as 'mysterious Zemer'. I acknowledge this is one of my more esoteric blog posts! But if it helped me find more joy in life, then perhaps it can help you too. It’s a little like setting a checkpoint in Hollow Knight you’ve successfully taken an otherwise forgotten part of your life (commuting) and made +1 memory within it. Take note of something to remember until the next time you sit on a bench. Please contact us if you want to publish a Hollow Knight HD wallpaper on our site. We hope you enjoy our growing collection of HD images to use as a background or home screen for your smartphone or computer. It’s hard to explain why or how this is useful, but it magically expands five seconds into a feeling much longer than that. A collection of the top 51 Hollow Knight HD wallpapers and backgrounds available for download for free. ![]() Hornet looks cool as she swings her needle around, against a moody backdrop. When you’re about to get up, count to five first. Here is our selection of the best Hollow Knight backgrounds and wallpapers. Gently adjust your posture and distribute your weight to be comfortably energy-neutral. 150+ Immerse yourself in the mesmerizing world of Hollow Knight with our collection of stunning wallpapers, animated gifs, and captivating fan art. What story do your surroundings tell? (this place is strangely silent given the location with the picnics here, this is a place where love often grows you’ve been going to this bus stop for 5+ years and you / the skyline’s changed so much etc) What imagery is happening in your surroundings? (the sun is between two buildings there are many birds on one roof, etc) Take note of everything in your surroundings, as if you’re inside a painting. ![]() You can also view the status of your package on this system, as well as see an estimated delivery time for eligible shipments. You will be able to see an estimated delivery time for eligible shipments if you use this system. You can also use FedEx Delivery Manager to track your packages. The package will then be loaded by the driver. When the package is marked as expected, the system will calculate the delivery time based on the package’s estimated delivery time. The driver then scans each package and adds it to the system. The package will be delivered to the shipping destination by the driver. When packages are loaded onto a truck, they are weighed according to their weight. GPS also allows FedEx to route its trucks more efficiently, which saves on fuel costs. This allows the company to keep track of its vehicles and ensure that packages are delivered on time. If the tracking number isn’t available, you can contact the courier company for more information. If your package hasn’t been scanned in a while, you can check the tracking number to see if it is still here. Because packages are scanned less frequently on the move, tracking them while they are traveling can be difficult. Tracking Your Fedex PackageįedEx has created a technology that allows packages to be scanned at various points between pickup and delivery. If a package has not been delivered, please contact the shipper to find out what happened. If your package has not received an update within 24 hours, please contact FedEx for assistance. Did you know? Using FedEx Delivery Manager® to track your package eliminates the need for a tracking number. What can I do? Even if you do not have a tracking number, you can still track your package using a reference number or a purchase order number. I don’t have a GPS tracking number and have no idea how to get my tracking number back. Why Is Fedex Ground Tracking Not Updating? Your FedEx Delivery Manager account can be accessed online as well. It includes tools to track and manage packages, create shipments, receive real-time alerts about deliveries, and much more. ![]() Can I See What Packages Are Coming To My House Fedex? and 8 p.m., Monday through Friday however, delivery can take place between 8 a.m. What Time Does Fedex Usually Deliver In My Area?įor residential deliveries, FedEx Express shipments only, and FedEx shipping can take place between 8 a.m. There are other ways to do this, in addition to FedEx InSight. Furthermore, a purchase order number, a customer reference number, an invoice, a bill of lading number (BOL), a part number, or a transportation control number (TCN) can be used by businesses. You can even find your package and track it by entering an address or name. Can You Search Fedex By Delivery Address? From there, you will be able to view your delivery map and track your package. Maximum weight allowed for each freight box is 1,200 lbs.If you need to find your FedEx delivery map, you can go to the FedEx website and log in to your account. Alaska, Hawaii, Puerto Rico, Canada and Mexico are not covered by FedEx Freight box rates. Use of the FedEx Freight box will supersede any negotiated pricing. Pricing is subject to the standard FedEx Freight 100 fuel surcharge. Exception: Item 404 (absolute minimum charge) will not apply as the FedEx Freight box is not discountable. Rates are subject to the General Rate Increase (GRI), and all accessorial charges in the FedEx Freight 100 Rules Tariff will apply. Customers with current pricing and/or non-U.S., non-Canada-based billing addresses are not eligible for the discount. Discounts are exclusive of any FedEx surcharges, premiums, minimums, accessorial charges or special handling fees. FedEx shipping discounts are off standard list rates and cannot be combined with other offers or discounts. and Canada, and also includes shipments to Alaska, Hawaii and Puerto Rico for the U.S. The discount applies to eligible FedEx Freight Priority and FedEx Freight Economy shipments within the contiguous U.S., shipments between the U.S. All services are subject to the terms and conditions of the FedEx Freight 100 Rules Tariff. *Applies to FXF PZONE and FXF EZONE rate customers only. ![]() It'd also mean you could stop gating different freak variations behind different difficulties as the plague territory system would balance blood freaks for even Green and Standard zones.īasically, plague territories are a stroke of genius that completely revitalised the game for me - but with a small tweak they could be even better. Not only that, but it'd make the Blood Plague and the regular zombie virus even more distinct both narratively and gameplay wise. I shouldn't need Scentblock to scavenge one diner down the street.īut! If plague freaks were limited in spawning outside of plague territory, this issue would be fixed. It makes me wonder why I bother leaving home as we're largely self sufficient and can keep on top of our needs through production alone. It's not quite as gloriously, murderously unfair as plague territory is, which means I'm surviving, but I'm also getting jumped by plague hordes and packs of blood ferals every time I leave the base. Through great efforts and the sacrifice of about one survivor per two plague hearts, I managed to entirely clear the town around the Lumber Mill, and move in, with the intention of making a safe-ish area to scavenge and live in. ![]() I recently moved a struggling Nightmare community into Lethal Providence Ridge, and have been loving it. Send me packs of six ferals if you really need toJust let me feel like I'm making appreciable, meaningful progress in the war against the blood plague. Undead Labs, you can even double their frequency if you want. Instead, have regular freaks spawn in cleared areas.
![]() Vertex42's Mileage Tracker was designed to track the business miles and the total miles so that you can calculate the "% Business Use." For Charity and Non Reimbursed Business Use In cases where the business use is less than 100%, only a percentage of the total expenses can be deducted. If the vehicle is owned and used 100% for business, then all of these costs can be deducted (see the IRS publication for more information about what costs can be deducted). The Actual Expenses deduction is used for "itemizing" the actual cost of owning, maintaining and using the vehicle for business purposes. The total deduction is then simply the mileage rate multiplied by the reimbursable miles. Use Vertex42's Mileage Tracker to track the miles. Actual expenses for things like gas, insurance and maintenance are not deducted, because they are factored into the mileage reimbursement rate. Under the Standard Mileage deduction, the miles are multiplied by the IRS deduction rate to determine the amount of the deductions. Regardless, both methods require accurate records be kept as evidence for the deductions. ![]() ![]() You should read the appropriate IRS publication about this, because there are certain requirements and qualifications associated with each of these methods. They can choose from the Standard Mileage deduction method or the Actual Car Expenses deduction method. Business owners have two options when it comes to deducting the car expenses. |
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